Coffee, tea, and cocoa in obesity prevention: Mechanisms of action and future prospectsBy:Wang, Qian ; Hu, Gui-Lin ; Qiu, Ming-Hua; Cao, Jun ; Xiong, Wen-YongCURRENT RESEARCH IN FOOD SCIENCEDOI:https://doi.org/10.1016/j.crfs.2024.100741Published:2024-06-06Abstract Obesity, a major public health problem, causes numerous complications that threaten human health and increase the socioeconom...
Sulfonamides as N-Centered Radical Precursors for C-N Coupling Reactions To Generate AmidinesBy: Deng, Guogang ; Chen, Zhuo ; Bai, Yifeng ; Zhang, Lening ; Xia, Dazhen ; Duan, Shengzu ; Chen, Wen ; Zhang, Hongbin ; Walsh, Patrick J. ; Yang, XiaodongOrganic LettersDOI:https://doi.org/10.1021/acs.orglett.4c01014Published:2024-04-30AbstractNitrogen-centered radicals (NCRs) are valuable intermedi...
Biswulfenioidins A-E, dioxygen-bridged abietane-type diterpenoid dimers with anti-Zika virus potential from Orthosiphon wulfenioidesBy:Tu, Wen-Chao ; Huang, Yong-Xiang ; Kong, Yuan-Lin ; Li, Bo ; Wang, Bin-Bao ; Dong, Tian-Hao ; Chen, Wei-Chi ; Zeb, Muhammad Aurang ; Li, Xiao-Li ; Liu, Mei-Feng ; Zheng, Chang-Bo ; Xiao, Wei-LieOrganic Chemistry FrontiersDOI:https://doi.org/10.1039/d4qo00619dPu...
Photoredox catalyzed hydroazolylation of alkenes via phosphoranyl radicalsBy: Zhu, Fan ; Qiao, Zhi ; He, Na ; Nong, Chunxiao ; He, Qiping ; Xi, Meilan ; Song, Xizhong ; Lin, Jun ; Chen, Jingbo ; Jin, YiOrganic Chemistry FrontiersDOI:https://doi.org/10.1039/d4qo00233dPublished:2024-05-14Abstract Herein, a general protocol for the hydroazolylation of alkenes with N-hydroxyl azoles is repo...
Cascade Rearrangement: Nitro Group-Participating Syntheses of 1,2,5-Thiadiazoles and 1,2,4-ThiadiazolonesBy:Li, Rui ; Liu, Jie ; Zhu, Tuo ; Zhou, Feng ; Zhang, HongbinJournal Of Organic ChemistryDOI:https://doi.org/10.1021/acs.joc.3c02623Published:2024-05-19AbstractA trifluoroacetic anhydride-mediated cascade process for the synthesis of thiadiazole derivatives is described. 1,2,5-Thiadiazole...
Carbazol-benzothiadiazole based D-A-D mesogens: Self-assembly and photophysical characteristicsBy:Mo, Miaoshui ; Guo, Zilong ; Chen, Shibo ; Ma, Tao ; Duan, Yuantang ; Yang, Yu ; Cheng, XiaohongJournal of Molecular LiquidsDOI:https://doi.org/10.1016/j.molliq.2024.124619Published:2024-05-01AbstractThree carbazole(C)-benzothiadiazole(B) based D -A -D mesogens CBC/n (n = 12, 16) and CTBTC/16 co...
Prins cyclization of 1,3-dioxinone: synthesis of 11-epi-badkhysinBy:Xu, Xiaoliang ; Hua, Ping;Xu, Yiren ; He, Baoqing ; Zhao, Jingfeng;Li, Liang ; Chen, Wen ; Zhang, HongbinOrganic Chemistry FrontiersDOI:https://doi.org/10.1039/d4qo00162aPublished:2024-04-16AbstractThe asymmetric synthesis of highly functional 11-epi-badkhysin has been accomplished using a structure-unit based approach. Key ...
Visible light-induced sulfonylation with sulfinates as closed-shell radical acceptorsBy: Hu, Dongyan ; Shen, Lei; Chaw, Su Su Htwe ; Liang, Kangjiang; Xia, ChengfengOrganic Chemistry FrontiersDOI:https://doi.org/10.1039/d4qo00370ePublished:2024-APRAbstract (Hetero)aryl sulfones possess wide biological activities and serve as important structural motifs in pharmaceuticals and agrochemical...
Phenylhydrazone anions excitation for the photochemical carbonylation of aryl iodides with aldehydesBy:Shen, Lei; Zhang, Yang ; Zhang, Linlin; Liu, Chuanwang ;Ma, Zhixian ; Liang, Kangjiang ; Xia, ChengfengChinese Chemical LettersDOI:https://doi.org/10.1016/j.cclet.2023.108742Published:2024—Apr. AbstractSpectroscopic investigations discovered that the in -situ generated phenylhydrazone anion...
Scandium-catalyzed chemoselective carbene insertion into N-H over S-H: access to o-alkylamine-diaryl disulfidesBy: Sun, Haoyany ; Pan, Junhong ; Zhao, Wenying ; Zhou, Tong ; Song, Xizhong ; Lin, Jun ; Jin, YiChemical CommunicationsDOI:https://doi.org/10.1039/d4cc00557kPublished:2024-04-02Abstract Herein, we report a scandium-catalyzed chemoselective carbene insertion into a N-H bond over...